1998•Molecular crystals and liquid crystals science technology. Section A, Molecular crystals and liquid crystals/Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystalsRequires access

Exciton Trapping Mechanism in Quasi-1D Molecular Chains (J-aggregates)

Yu. V. Malyukin, O. G. Tovmachenko, G. S. Katrich, S. L. Efimova, Klaus Kemnitz

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Abstract

The exciton trapping mechanism by impurity centers in quasi-1D molecular chains (J-aggregates) is studied for the binary solutions of dimethylformamide and water. It is determined that the exciton energy transfer is occurring due to the dipole-dipole mechanism. The influence of the exciton self-trapping process on the trapping efficiency was found. It is shown that the exciton trapping occurs mainly owing to free excitons. The critical radius and trapping rate were determined.

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What this paper is about

The exciton trapping mechanism by impurity centers in quasi-1D molecular chains (J-aggregates) is studied for the binary solutions of dimethylformamide and water. It is determined that the exciton energy transfer is occurring due to the dipole-dipole mechanism. The influence of the exciton self-trapping process on the trapping efficiency was found. It is shown that the exciton trapping occurs mainly owing to free excitons. The critical radius and trapping rate were determined.

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Available abstract

The exciton trapping mechanism by impurity centers in quasi-1D molecular chains (J-aggregates) is studied for the binary solutions of dimethylformamide and water. It is determined that the exciton energy transfer is occurring due to the dipole-dipole mechanism. The influence of the exciton self-trapping process on the trapping efficiency was found. It is shown that the exciton trapping occurs mainly owing to free excitons. The critical radius and trapping rate were determined.

Key concepts: Exciton, Trapping, Dipole, Chemical physics, RADIUS, Molecular physics, Condensed matter physics, Chemistry

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