Exciton Trapping Mechanism in Quasi-1D Molecular Chains (J-aggregates)
Yu. V. Malyukin, O. G. Tovmachenko, G. S. Katrich, S. L. Efimova, Klaus Kemnitz
Abstract
Yu. V. Malyukin, O. G. Tovmachenko, G. S. Katrich, S. L. Efimova, Klaus Kemnitz
Abstract
The exciton trapping mechanism by impurity centers in quasi-1D molecular chains (J-aggregates) is studied for the binary solutions of dimethylformamide and water. It is determined that the exciton energy transfer is occurring due to the dipole-dipole mechanism. The influence of the exciton self-trapping process on the trapping efficiency was found. It is shown that the exciton trapping occurs mainly owing to free excitons. The critical radius and trapping rate were determined.
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The exciton trapping mechanism by impurity centers in quasi-1D molecular chains (J-aggregates) is studied for the binary solutions of dimethylformamide and water. It is determined that the exciton energy transfer is occurring due to the dipole-dipole mechanism. The influence of the exciton self-trapping process on the trapping efficiency was found. It is shown that the exciton trapping occurs mainly owing to free excitons. The critical radius and trapping rate were determined.
Key concepts: Exciton, Trapping, Dipole, Chemical physics, RADIUS, Molecular physics, Condensed matter physics, Chemistry