The synthesis and liquid crystal properties of certain 1-(4′-n-alkoxy-2,2′,3,3′,5,5′,6,6′-octafluorobiphenyl-4-yl)- 2-(trans-4-n-pentylcyclohexyl)-ethanes and -ethenes
David J. Byron, Avtar Singh Matharu, Robert Curtis Wilson
Abstract
David J. Byron, Avtar Singh Matharu, Robert Curtis Wilson
Abstract
The synthesis and liquid crystal properties of eight members of the homologous series of 1-(4′-n-alkoxy-2,2′,3,3′,5,5′,6,6′-octafluorobiphenyl-4-yl)-2-(trans-4-n-pentylcyclohexyl)-ethanes and eight members of the corresponding -ethanes, which have the E-configuration, are reported. These compounds are nematic, the ethenes having a considerably mesophase higher thermal stability than the analogous ethanes.
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The synthesis and liquid crystal properties of eight members of the homologous series of 1-(4′-n-alkoxy-2,2′,3,3′,5,5′,6,6′-octafluorobiphenyl-4-yl)-2-(trans-4-n-pentylcyclohexyl)-ethanes and eight members of the corresponding -ethanes, which have the E-configuration, are reported. These compounds are nematic, the ethenes having a considerably mesophase higher thermal stability than the analogous ethanes.
Key concepts: Alkoxy group, Liquid crystal, Homologous series, Mesophase, Materials science, Thermal stability, Organic chemistry, Medicinal chemistry