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1990•Bulletin of the Chemical Society of JapanRequires access

Cooperation of Imidazolyl and Carboxylate Residues for Efficient Cleavage of Bis(nitrophenyl) Hydrogenphosphates

Makoto Komiyama

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Abstract

Abstract 4-Imidazoleacetate efficiently catalyzes the cleavage of bis(2,4-dinitrophenyl) hydrogenphosphate and bis(4-nitrophenyl) hydrogenphosphate (1600 and 15000 fold acceleration at pH 8.0 at 1.0 mol dm−3). The effective catalysis is ascribed to the intramolecular cooperation of the imidazolyl and the carboxylate residues.

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What this paper is about

Abstract 4-Imidazoleacetate efficiently catalyzes the cleavage of bis(2,4-dinitrophenyl) hydrogenphosphate and bis(4-nitrophenyl) hydrogenphosphate (1600 and 15000 fold acceleration at pH 8.0 at 1.0 mol dm−3). The effective catalysis is ascribed to the intramolecular cooperation of the imidazolyl and the carboxylate residues.

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Available abstract

Abstract 4-Imidazoleacetate efficiently catalyzes the cleavage of bis(2,4-dinitrophenyl) hydrogenphosphate and bis(4-nitrophenyl) hydrogenphosphate (1600 and 15000 fold acceleration at pH 8.0 at 1.0 mol dm−3). The effective catalysis is ascribed to the intramolecular cooperation of the imidazolyl and the carboxylate residues.

Key concepts: Chemistry, Carboxylate, Cleavage (geology), Medicinal chemistry, Stereochemistry, Combinatorial chemistry, Engineering, Fracture (geology)

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Cooperation of Imidazolyl and Carboxylate Residues for Efficient Cleavage of Bis(nitrophenyl) Hydrogenphosphates — Research Paper | ScholarLens