Temperatures and isotopic evolution of silicic magmas, Taupo Volcanic Zone and Coromandel, New Zealand

Abstract A new set of oxygen and strontium isotope data on rhyolitic lavas and ignimbrites of the Taupo Volcanic Zone (TVZ) and the Coromandel Peninsula provides new limits for petrogenetic models. For oxygen isotopes, the rock matrix is frequently altered, so that values for magma need to be phenocryst based. Within TVZ a trend towards more negative 8 18 O values for more recent magmas appears likely (average before about 1 Ma and for Coromandel near 8.0%o; after 1 Ma near 7.5%o). This could indicate the gradual removal of supracrustal contaminants from the zones of magma accumulation and extrusion. Similar trends within Coromandel cannot yet be resolved. A generally positive correlation is found for oxygen and strontium isotopes of magmas. Most magmas have a limited range of isotopic values, which then becomes a useful fingerprint (e.g., the Mamaku, Matahina, and Waiotapu Ignimbrites). A narrow range of eruption temperatures of 880 ± 60°C is derived from quartz‐plagioclase fractionations of 0.98 ± 0.25‰ δ 18 O for 15 magmas. Some δ 18 O values of quartz and feldspar phenocrysts are sufficiently low to suggest interaction between surface water and magma. However, large negative oxygen isotope anomalies (such as known from Yellowstone), could be no more than partially concealed by the isotopically less depleted meteoric water of New Zealand, and have not yet been found in New Zealand.