Desiliconization Reaction of Pig Iron with MnO Containing Blast Furnace Slag under Pressurized and Coke-coexisting Condition
Chisato Yamagata, Yoshimasa Kajiwara, Shinichi Suyama
Abstract
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Chisato Yamagata, Yoshimasa Kajiwara, Shinichi Suyama
Abstract
Open-access reader
For the clarification of the mechanism of the desiliconization reaction of pig iron with MnO containing blast furnace slag under pressurized and coke-coexisting condition, fundamental experiments were performed by the use of a pressurized high frequency furnace. Based on the experimental results, a mathematical simulation model with consideration of the direct reduction reaction as the coupled reaction with the desiliconization reaction was developed and applied to the quantitative evaluation of the desiliconization reaction with MnO and FeO containing slag.The following knowledge was obtained.(1) Under the existence of coke, MnO and FeO are partly consumed by the coupled reaction of direct reduction reaction and the desiliconization reaction is restrained.(2) The increase of pressure, with the presence of coke, results in the indirect enhancement of the desiliconization reaction through the restraint of the direct reduction reaction.(3) The effect of the charging of manganese ore on the increase of Mn content and the decrease of Si content in pig iron was quantitatively evaluated by an another simulation model for blast furnace hearth.
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For the clarification of the mechanism of the desiliconization reaction of pig iron with MnO containing blast furnace slag under pressurized and coke-coexisting condition, fundamental experiments were performed by the use of a pressurized high frequency furnace. Based on the experimental results, a mathematical simulation model with consideration of the direct reduction reaction as the coupled reaction with the desiliconization reaction was developed and applied to the quantitative evaluation of the desiliconization reaction with MnO and FeO containing slag.The following knowledge was obtained.(1) Under the existence of coke, MnO and FeO are partly consumed by the coupled reaction of direct reduction reaction and the desiliconization reaction is restrained.(2) The increase of pressure, with the presence of coke, results in the indirect enhancement of the desiliconization reaction through the restraint of the direct reduction reaction.(3) The effect of the charging of manganese ore on the increase of Mn content and the decrease of Si content in pig iron was quantitatively evaluated by an another simulation model for blast furnace hearth.
Key concepts: Pig iron, Blast furnace, Coke, Ground granulated blast-furnace slag, Metallurgy, Slag (welding), Manganese, Chemical reaction