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1986•Journal of Macromolecular Science Part A - ChemistryRequires access

Arylsulfone Derivatives of Polystyrene

Arijit Dasgupta, Everett R. Santee, H. James Harwood

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Abstract

Arylsulfonyl chlorides have been found to react quantitatively with polystyrene in the presence of Friedel-Crafts catalysts at room temperature. Polymers having the general structure I, where R = H, CH3, Cl, Br, F and OCH3, were prepared and characterized by NMR and IR spectroscopy, differential scanning calorimetry (DSC), gel permeation chromatography (GPC), and thermogravimetric analysis (TGA).

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What this paper is about

Arylsulfonyl chlorides have been found to react quantitatively with polystyrene in the presence of Friedel-Crafts catalysts at room temperature. Polymers having the general structure I, where R = H, CH3, Cl, Br, F and OCH3, were prepared and characterized by NMR and IR spectroscopy, differential scanning calorimetry (DSC), gel permeation chromatography (GPC), and thermogravimetric analysis (TGA).

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Available abstract

Arylsulfonyl chlorides have been found to react quantitatively with polystyrene in the presence of Friedel-Crafts catalysts at room temperature. Polymers having the general structure I, where R = H, CH3, Cl, Br, F and OCH3, were prepared and characterized by NMR and IR spectroscopy, differential scanning calorimetry (DSC), gel permeation chromatography (GPC), and thermogravimetric analysis (TGA).

Key concepts: Thermogravimetric analysis, Polystyrene, Differential scanning calorimetry, Gel permeation chromatography, Polymer chemistry, Polymer, Chemistry, Materials science

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