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Gas Electron Diffraction Study of the Molecular Structure of Di-2-pyridyl Sulphide

Béla Rozsondai, István Hargittai, Giuseppe Pappalardo

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Abstract

Abstract The gas-phase electron diffraction study of di-2-pyridyl sulphide has yielded rg(S-C) 1.786 ± 0.004 Å and ∢ C-S-C 104.4 ± 1.7°. The dimensions of the pyridyl groups were found to be consistent with those of free pyridine molecules. Models with various conformational properties could be used to approximate the experimental data.

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Abstract The gas-phase electron diffraction study of di-2-pyridyl sulphide has yielded rg(S-C) 1.786 ± 0.004 Å and ∢ C-S-C 104.4 ± 1.7°. The dimensions of the pyridyl groups were found to be consistent with those of free pyridine molecules. Models with various conformational properties could be used to approximate the experimental data.

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Abstract The gas-phase electron diffraction study of di-2-pyridyl sulphide has yielded rg(S-C) 1.786 ± 0.004 Å and ∢ C-S-C 104.4 ± 1.7°. The dimensions of the pyridyl groups were found to be consistent with those of free pyridine molecules. Models with various conformational properties could be used to approximate the experimental data.

Key concepts: Electron diffraction, Gas phase, Molecule, Diffraction, Pyridine, Crystallography, Gas electron diffraction, Chemistry

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