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1979•Russian Chemical ReviewsOpen access

Phosgene in the Chemistry of Organosilicon Compounds

В. Ф. Миронов, V. D. Sheludyakov, V. P. KOZYUKOV

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Abstract

A systematic account of data concerning the problems of the synthesis of a wide variety of organic and organosilicon derivatives of carbonic acid (chlorocarbonates, carbonates, isocyanates, carbodiimides, acylcarbamoyl chlorides, etc.) by the reaction of phosgene with N- and O-silyl-substituted amines, amides, diazoles, iminoesters, and ethers derived from alcohols, glycols, etc. is given for the first time. The bibliography includes 113 references.

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A systematic account of data concerning the problems of the synthesis of a wide variety of organic and organosilicon derivatives of carbonic acid (chlorocarbonates, carbonates, isocyanates, carbodiimides, acylcarbamoyl chlorides, etc.) by the reaction of phosgene with N- and O-silyl-substituted amines, amides, diazoles, iminoesters, and ethers derived from alcohols, glycols, etc. is given for the first time. The bibliography includes 113 references.

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Available abstract

A systematic account of data concerning the problems of the synthesis of a wide variety of organic and organosilicon derivatives of carbonic acid (chlorocarbonates, carbonates, isocyanates, carbodiimides, acylcarbamoyl chlorides, etc.) by the reaction of phosgene with N- and O-silyl-substituted amines, amides, diazoles, iminoesters, and ethers derived from alcohols, glycols, etc. is given for the first time. The bibliography includes 113 references.

Key concepts: Organosilicon, Chemistry, Phosgene, Organic chemistry, Silylation, Carbonic acid, Hydrofluoric acid, Catalysis

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