2013Journal of Propulsion and PowerRequires access

Investigation of Composite Propellant Based on Hydroxyl Terminated Polybutadiene–1-Chloro-2,4-Dinitrobenzene

Mohamed Abdullah, F. Gholamian, M. R. Zareiee

Open publisher page 7 citations

Abstract

When attaching 1-chloro-2,4-dinitrobenzene in the hydroxyl terminated polybutadiene backbone, a new energetic prepolymer will be formed without destroying the physicochemical properties, fluidity, and microstructure of hydroxyl terminated polybutadiene. This paper discusses a new composite propellant based on hydroxyl terminated polybutadiene–1-chloro-2,4-dinitrobenzene binder. This solid propellant has been formulated and characterized. The results have shown a 35% increase in burning rate and density. In addition, they exhibited good mechanical and rheological properties over a wide range of temperatures (similar to hydroxyl terminated polybutadiene propellant). Based on the experiments carried out, this prepolymer seems promising as an energetic binder to increase the density-specific impulse for solid propellants and to substitute for both hydroxyl terminated polybutadiene and for recent energetic binders.

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What this paper is about

When attaching 1-chloro-2,4-dinitrobenzene in the hydroxyl terminated polybutadiene backbone, a new energetic prepolymer will be formed without destroying the physicochemical properties, fluidity, and microstructure of hydroxyl terminated polybutadiene. This paper discusses a new composite propellant based on hydroxyl terminated polybutadiene–1-chloro-2,4-dinitrobenzene binder. This solid propellant has been formulated and characterized. The results have shown a 35% increase in burning rate and density. In addition, they exhibited good mechanical and rheological properties over a wide range of temperatures (similar to hydroxyl terminated polybutadiene propellant). Based on the experiments carried out, this prepolymer seems promising as an energetic binder to increase the density-specific impulse for solid propellants and to substitute for both hydroxyl terminated polybutadiene and for recent energetic binders.

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Available abstract

When attaching 1-chloro-2,4-dinitrobenzene in the hydroxyl terminated polybutadiene backbone, a new energetic prepolymer will be formed without destroying the physicochemical properties, fluidity, and microstructure of hydroxyl terminated polybutadiene. This paper discusses a new composite propellant based on hydroxyl terminated polybutadiene–1-chloro-2,4-dinitrobenzene binder. This solid propellant has been formulated and characterized. The results have shown a 35% increase in burning rate and density. In addition, they exhibited good mechanical and rheological properties over a wide range of temperatures (similar to hydroxyl terminated polybutadiene propellant). Based on the experiments carried out, this prepolymer seems promising as an energetic binder to increase the density-specific impulse for solid propellants and to substitute for both hydroxyl terminated polybutadiene and for recent energetic binders.

Key concepts: Hydroxyl-terminated polybutadiene, Polybutadiene, Propellant, Prepolymer, Materials science, Composite number, Polymer chemistry, Composite material

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