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Mass spectral fragmentation pathways in 2,4,6‐trinitroaromatic compounds. A tandem mass spectrometric collision induced dissociation study

Jehuda Yinon

Abstract

Abstract A collision induced dissociation study of a series of 2,4,6‐trinitroaromatic compounds was carried out using a tandem BB mass spectrometer. Fragmentation pathways of the compounds were determined in the electron impact mode. It was found that dominant fragmentation pathways include loss of OH˙ due to an ortho effect and loss of NO˙ due to the formation of resonance‐stabilized products.

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Key concepts: Fragmentation (computing), Collision-induced dissociation, Dissociation (chemistry), Chemistry, Tandem mass spectrometry, Electron ionization, Tandem, Mass spectrometry