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Dicyclometalated Mononuclear Bis(carbene)platinum(IV) Complexes

Shiwei Zhang, Shigetoshi Takahashi

Abstract

The consecutive reaction of bis(arylisocyanide)platinum(II) complex 1 with a primary amine and then chloroform gave novel dicyclometalated mononuclear bis(carbene)platinum(IV) complex 2 having an octahedral structure, which may be formed via monocyclometalated bis(carbene)platinum(II) complex 3 and dicyclometalated bis(carbene)platinum(IV) complex 4 .

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Key concepts: Carbene, Chemistry, Platinum, Octahedron, Chloroform, Amine gas treating, Medicinal chemistry, Polymer chemistry