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TRIFLUOROMETHYLTHIOLATION OF NORBORNENE

S. Munavalli, R. K. Rohrbaugh, George W. Wagner, H. D. Durst, Frederick R. Longo

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Abstract

Treatment of norbornene with trifluoromethylsulfenyl chloride at −80°C furnishes, in addition to trifluoromethylthionortricyclane, four isomeric (chloro) (trifluoromethylthio)-norbornanes and bis-(2, 6-trifluoromethylthio)norbornane. The probable mechanism of the formation of the various compounds via free radical intermediates and their mass spectral characterization are described in this communication.

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What this paper is about

Treatment of norbornene with trifluoromethylsulfenyl chloride at −80°C furnishes, in addition to trifluoromethylthionortricyclane, four isomeric (chloro) (trifluoromethylthio)-norbornanes and bis-(2, 6-trifluoromethylthio)norbornane. The probable mechanism of the formation of the various compounds via free radical intermediates and their mass spectral characterization are described in this communication.

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Available abstract

Treatment of norbornene with trifluoromethylsulfenyl chloride at −80°C furnishes, in addition to trifluoromethylthionortricyclane, four isomeric (chloro) (trifluoromethylthio)-norbornanes and bis-(2, 6-trifluoromethylthio)norbornane. The probable mechanism of the formation of the various compounds via free radical intermediates and their mass spectral characterization are described in this communication.

Key concepts: Norbornane, Norbornene, Chemistry, Chloride, Organic chemistry, Copolymer, Polymer

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