Gold‐Catalyzed 6‐Exo‐Dig Cycloisomerization: A Versatile Approach to Functionalized Phenanthrenes
Chao Shu, Long Li, Chengbin Chen, Hong‐Cheng Shen, Long‐Wu Ye
Abstract
Chao Shu, Long Li, Chengbin Chen, Hong‐Cheng Shen, Long‐Wu Ye
Abstract
A novel gold-catalyzed 6-exo-dig cycloisomerization of o-propargylbiaryls has been developed that provides ready access to functionalized phenanthrenes in largely good to excellent yields. Notable features of this method are readily available starting materials, mild reaction conditions, and broad substrate scope.
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A novel gold-catalyzed 6-exo-dig cycloisomerization of o-propargylbiaryls has been developed that provides ready access to functionalized phenanthrenes in largely good to excellent yields. Notable features of this method are readily available starting materials, mild reaction conditions, and broad substrate scope.
Key concepts: Cycloisomerization, Phenanthrenes, Catalysis, Substrate (aquarium), Scope (computer science), Chemistry, Combinatorial chemistry, Dig