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Synthesis of Allenes by Palladium-Catalyzed Cross-Coupling Reaction of Organoboron Compounds with Propargylic Carbonates: Transmetallation of Organoboron Compounds with (Alkoxo)palladium Complexes Under Neutral Conditions

Tsukasa Moriya, Norio Miyaura, Akira K. Suzuki

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Abstract

All articles of this category The palladium-catalyzed cross-coupling reaction of propargylic carbonates with organoboron compounds such as 1-alkenyl, 1-alkynyl, and arylboronic acids or their esters and 9-alkyl-9-BBN produced allene derivatives in high yields. The electronic effects on the boron-palladium transmetallation reaction which proceeds through (alkoxo)palladium(II) intermediates are also discussed.

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All articles of this category The palladium-catalyzed cross-coupling reaction of propargylic carbonates with organoboron compounds such as 1-alkenyl, 1-alkynyl, and arylboronic acids or their esters and 9-alkyl-9-BBN produced allene derivatives in high yields. The electronic effects on the boron-palladium transmetallation reaction which proceeds through (alkoxo)palladium(II) intermediates are also discussed.

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Available abstract

All articles of this category The palladium-catalyzed cross-coupling reaction of propargylic carbonates with organoboron compounds such as 1-alkenyl, 1-alkynyl, and arylboronic acids or their esters and 9-alkyl-9-BBN produced allene derivatives in high yields. The electronic effects on the boron-palladium transmetallation reaction which proceeds through (alkoxo)palladium(II) intermediates are also discussed.

Key concepts: Transmetalation, Palladium, Chemistry, Allene, Organoboron compounds, Catalysis, Organic chemistry, Medicinal chemistry

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Synthesis of Allenes by Palladium-Catalyzed Cross-Coupling Reaction of Organoboron Compounds with Propargylic Carbonates: Transmetallation of Organoboron Compounds with (Alkoxo)palladium Complexes Under Neutral Conditions — Research Paper | ScholarLens