2013•Functional Materials LettersRequires access
HYDROTHERMAL SYNTHESIS, CRYSTAL STRUCTURE AND ELECTROCHEMICAL BEHAVIOR OF 2D HYBRID COORDINATION POLYMER
Weiqiang Fan, Lin Sen Zhu, Weidong Shi, Fuxiao Chen, Hong‐Ye Bai, Shuyan Song, Yongsheng Yan
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Abstract
A novel metal-organic coordination polymer [Cu(phen)(L)0.5(H2O)]n (H4L = (N,N′-5,5′-bis(isophthalic acid)-p-xylylenediamine, and phen = 1,10-phenanthroline) has been hydrothermally synthesized and characterized by elemental analysis, IR, TGA, and single-crystal X-ray diffraction. The crystallographic data show that the title compound crystallizes in monoclinic space group P21/n with a = 10.682(2), b = 15.682(3), c = 11.909(2) Å, β = 91.39(3)°, V = 1994.3(7) Å3, C24H17CuN3O5 , Mr = 490.95, Dc = 1.635 g/cm3, F(000) = 1004, Z = 4, μ( MoK α) = 1.141 mm-1, the final R = 0.0418 and wR = 0.0983 for 3578 observed reflections (I > 2σ(I)). The structural analyses reveal that the title compound exhibits shows a 2D layer structure, which are further linked by hydrogen bonding interactions to form a three-dimensional supramolecular network. In addition, the thermal stability and electrochemical behavior of title compound has been studied. CCDC: 900413.