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1966•Journal of the Chemical Society A Inorganic Physical TheoreticalRequires access

Chemistry of the metal carbonyls. Part XXXVI. Carbonyl(organothio)-manganese and -rhenium complexes

Alan G. Osborne, F. G. A. Stone

Open publisher page 41 citations

Abstract

Pentacarbonyl(hydrido)-manganese and -rhenium react with pentafluorobenzenethiol and benzenethiol to give the complexes C6F5S·M(CO)5(M = Mn or Re) and [RS·M(CO)4]2(M = Mn or Re; R = C6F5 or C6H5). By treating carbonyl(halogeno)-complexes of manganese and rhenium with thiols, a series of trimeric compounds [RS·M(CO)3]3(M = Mn or Re; R = C2H5 or n-C4H9, C6H5) has been obtained.

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What this paper is about

Pentacarbonyl(hydrido)-manganese and -rhenium react with pentafluorobenzenethiol and benzenethiol to give the complexes C6F5S·M(CO)5(M = Mn or Re) and [RS·M(CO)4]2(M = Mn or Re; R = C6F5 or C6H5). By treating carbonyl(halogeno)-complexes of manganese and rhenium with thiols, a series of trimeric compounds [RS·M(CO)3]3(M = Mn or Re; R = C2H5 or n-C4H9, C6H5) has been obtained.

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Available abstract

Pentacarbonyl(hydrido)-manganese and -rhenium react with pentafluorobenzenethiol and benzenethiol to give the complexes C6F5S·M(CO)5(M = Mn or Re) and [RS·M(CO)4]2(M = Mn or Re; R = C6F5 or C6H5). By treating carbonyl(halogeno)-complexes of manganese and rhenium with thiols, a series of trimeric compounds [RS·M(CO)3]3(M = Mn or Re; R = C2H5 or n-C4H9, C6H5) has been obtained.

Key concepts: Rhenium, Manganese, Chemistry, Metal carbonyl, Metal, Medicinal chemistry, Inorganic chemistry, Photochemistry

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Chemistry of the metal carbonyls. Part XXXVI. Carbonyl(organothio)-manganese and -rhenium complexes — Research Paper | ScholarLens