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The Zeeman Effect in the Molecular Spectra of Hydrogen

G. H. Dieke, Shawn Cunningham, Francis T. Byrne

Open publisher page 17 citations

Abstract

The Zeeman effect in the molecular spectrum of hydrogen was observed for all six isotopic species for a field strength of nearly 35 000 gauss. Several thousand lines show modification in the field with many completely resolved patterns. When there is no $L$ decoupling, the splittings are represented by the simple theory. When there is $L$ decoupling, the splittings may be helpful for the evaluation of the degree of $L$ decoupling and other interactions. Abnormal effects occur for some lines which are related to the Paschen-Back effect in atomic spectra.In a molecular spectrum of this type the observed Zeeman effects are a valuable aid for the classification and interpretation of the lines fully as much as in atomic spectra.

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What this paper is about

The Zeeman effect in the molecular spectrum of hydrogen was observed for all six isotopic species for a field strength of nearly 35 000 gauss. Several thousand lines show modification in the field with many completely resolved patterns. When there is no $L$ decoupling, the splittings are represented by the simple theory. When there is $L$ decoupling, the splittings may be helpful for the evaluation of the degree of $L$ decoupling and other interactions. Abnormal effects occur for some lines which are related to the Paschen-Back effect in atomic spectra.In a molecular spectrum of this type the observed Zeeman effects are a valuable aid for the classification and interpretation of the lines fully as much as in atomic spectra.

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Available abstract

The Zeeman effect in the molecular spectrum of hydrogen was observed for all six isotopic species for a field strength of nearly 35 000 gauss. Several thousand lines show modification in the field with many completely resolved patterns. When there is no $L$ decoupling, the splittings are represented by the simple theory. When there is $L$ decoupling, the splittings may be helpful for the evaluation of the degree of $L$ decoupling and other interactions. Abnormal effects occur for some lines which are related to the Paschen-Back effect in atomic spectra.In a molecular spectrum of this type the observed Zeeman effects are a valuable aid for the classification and interpretation of the lines fully as much as in atomic spectra.

Key concepts: Zeeman effect, Decoupling (probability), Spectral line, Physics, Atomic physics, Hydrogen, Hydrogen spectral series, Hydrogen molecule

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