1987•Bulletin of the Chemical Society of JapanRequires access

Re-extraction Behavior of Nitrosyl Ruthenium Complex in Tributyl Phosphate–Dodecane Solvent System

Akira Sasahira, Tatsuo Izumida, Fumio Kawamura

Abstract

Abstract A re-extraction of the nitrosyl ruthenium complex from a tributyl phosphate-dodecane solvent system to a nitric acid solution was carried out. A longer aging of the organic phase before re-extraction lowered the re-extraction yield, while nitric acid extracted into the organic phase increased it. These results could be explained using a model with two organic species.

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Key concepts: Chemistry, Tributyl phosphate, Ruthenium, Dodecane, Extraction (chemistry), Phosphate, Solvent extraction, Solvent