2014•The Journal of Organic ChemistryRequires access

Synthesis of gem-Difluorinated Nitroso Compounds

Vladimir O. Smirnov, Марина И. Стручкова, Dmitry E. Arkhipov, Alexander Aleksandrovich Korlyukov, Alexander D. Dilman

Abstract

A method for the synthesis of gem-difluorinated nitroso compounds is described. The reaction involves interaction of organozinc reagents with (bromodifluoromethyl)trimethylsilane followed by nitrosation of difluorinated organozinc species with an n-butyl nitrite/chlorotrimethylsilane system.

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Key concepts: Chemistry, Nitrosation, Trimethylsilane, Nitroso Compounds, Nitroso, Reagent, Nitrite, Organic chemistry