The Polarographic Determination of 1-[4'-(Phenylazo)phenyl]-3,3-dimethyltriazene
Jiřı́ Barek, Dana Dřevínková, Jiřı́ Zima, Arnold G. Fogg
Abstract
Jiřı́ Barek, Dana Dřevínková, Jiřı́ Zima, Arnold G. Fogg
Abstract
A study has been made of the polarographic behaviour of genotoxic 1-[4'-(phenylazo)phenyl]-3,3-dimethyltriazene in mixed water-methanol medium. A mechanism has been proposed for its polarographic reduction and optimal conditions have been found for its determination by tast polarography in the concentration range 1 . 10-4 - 2 . 10-6 mol l-1 and using differential pulse polarography in the concentration range 1 . 10-4 - 2 . 10-7 mol l-1.
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A study has been made of the polarographic behaviour of genotoxic 1-[4'-(phenylazo)phenyl]-3,3-dimethyltriazene in mixed water-methanol medium. A mechanism has been proposed for its polarographic reduction and optimal conditions have been found for its determination by tast polarography in the concentration range 1 . 10-4 - 2 . 10-6 mol l-1 and using differential pulse polarography in the concentration range 1 . 10-4 - 2 . 10-7 mol l-1.
Key concepts: Polarography, Chemistry, Methanol, Pulse (music), Peak current, Analytical Chemistry (journal), Electrochemistry, Chromatography