Sintering Additives to Eliminate Interphases in Cordierite Ceramics

Effects of the sintering additives CeO 2 and K 2 O on eliminating interphases of cristobalite and spinel were studied by means of XRD, SEM/energy‐dispersive spectrometer, and TMA techniques to obtain high cordierite contents. Adding 4 wt% CeO 2 significantly stimulates the conversion of cristobalite to cordierite, depresses spinel formation and yields less glassy phase. It is helpful to prepare a ceramic with a high content of cordierite and a low thermal expansion coefficient when sintered at 1400°C for 3 h. Addition of 1–2 wt% K 2 O results in a large amount of glassy phase and is less effective in eliminating the interphases.