1979Journal of Physics of the EarthOpen access

Thermal expansion of single-crystal manganosite.

Isao Suzuki, Shin-ichi OKAJIMA, Kiyoshi Seya

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Abstract

Thermal expansion of manganosite MnO at temperatures between 20°C and 850°C has been carefully determined by a dilatometric technique. The theory of thermal expansion by Gruneisen is improved and the acquired data are analyzed to derive the harmonic and anharmonic parameters of MnO. Gruneisen's parameter γ is 1.56, Debye temperature is 441 K, and pressure derivative of bulk modulus is 7. The volume expansion coefficient is 34.3×10-6/K at 20°C and 47.1×10-6/K at 850°C; almost the same in magnitude to those of MgO and FeO.

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Thermal expansion of manganosite MnO at temperatures between 20°C and 850°C has been carefully determined by a dilatometric technique. The theory of thermal expansion by Gruneisen is improved and the acquired data are analyzed to derive the harmonic and anharmonic parameters of MnO. Gruneisen's parameter γ is 1.56, Debye temperature is 441 K, and pressure derivative of bulk modulus is 7. The volume expansion coefficient is 34.3×10-6/K at 20°C and 47.1×10-6/K at 850°C; almost the same in magnitude to those of MgO and FeO.

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Available abstract

Thermal expansion of manganosite MnO at temperatures between 20°C and 850°C has been carefully determined by a dilatometric technique. The theory of thermal expansion by Gruneisen is improved and the acquired data are analyzed to derive the harmonic and anharmonic parameters of MnO. Gruneisen's parameter γ is 1.56, Debye temperature is 441 K, and pressure derivative of bulk modulus is 7. The volume expansion coefficient is 34.3×10-6/K at 20°C and 47.1×10-6/K at 850°C; almost the same in magnitude to those of MgO and FeO.

Key concepts: Thermal expansion, Anharmonicity, Grüneisen parameter, Bulk modulus, Debye model, Thermodynamics, Volume (thermodynamics), Materials science

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