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1976•Journal of the Chemical Society Chemical CommunicationsRequires access

Controlling the outcome of a carbonium ion reaction: the use of a trimethylsilyl group to dictate the formation of a specific olefin

Ian Fleming, Andrew Pearce, Roger L. Snowden

Open publisher page 37 citations

Abstract

The carbonium ions (2, R = SiMe3) and (6, R = SiMe3) give only the olefins (4) and (7), respectively, in contrast to the reactions of the carbonium ions (2, R = H) and (6, R = H).

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What this paper is about

The carbonium ions (2, R = SiMe3) and (6, R = SiMe3) give only the olefins (4) and (7), respectively, in contrast to the reactions of the carbonium ions (2, R = H) and (6, R = H).

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OpenAlex reports 37 citations for this work. Citation counts describe recorded attention and do not establish research quality.

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Available abstract

The carbonium ions (2, R = SiMe3) and (6, R = SiMe3) give only the olefins (4) and (7), respectively, in contrast to the reactions of the carbonium ions (2, R = H) and (6, R = H).

Key concepts: Carbonium ion, Chemistry, Trimethylsilyl, Ion, Olefin fiber, Group (periodic table), Medicinal chemistry, Photochemistry

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