2009Advances in Cement ResearchOpen access

Study of the pozzolanic reaction kinetics in sugar cane bagasse–clay ash/calcium hydroxide system: kinetic parameters and pozzolanic activity

E. Villar-Cociña, M. Frías Rojas, Eduardo Valencia Morales, Holmer Savastano

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Abstract

This paper presents a study of the pozzolanic reaction kinetics between calcium hydroxide and a mixture of sugar cane bagasse with 20 and 30% of clay, burned at 800 and 1000°C (SCBCA) by electrical conductivity measurements. A kinetic–diffusive model produced in previous studies by some of the authors was used. The model was fitted to the experimental data, which allowed the computation of the kinetic parameters of the pozzolanic reaction (reaction rate constant and free energy of activation) that rigorously characterised the pozzolanic activity of the materials. The results show that SCBCA demonstrated reactivity and good pozzolanic qualities in the range 800–1000°C.

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This paper presents a study of the pozzolanic reaction kinetics between calcium hydroxide and a mixture of sugar cane bagasse with 20 and 30% of clay, burned at 800 and 1000°C (SCBCA) by electrical conductivity measurements. A kinetic–diffusive model produced in previous studies by some of the authors was used. The model was fitted to the experimental data, which allowed the computation of the kinetic parameters of the pozzolanic reaction (reaction rate constant and free energy of activation) that rigorously characterised the pozzolanic activity of the materials. The results show that SCBCA demonstrated reactivity and good pozzolanic qualities in the range 800–1000°C.

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Available abstract

This paper presents a study of the pozzolanic reaction kinetics between calcium hydroxide and a mixture of sugar cane bagasse with 20 and 30% of clay, burned at 800 and 1000°C (SCBCA) by electrical conductivity measurements. A kinetic–diffusive model produced in previous studies by some of the authors was used. The model was fitted to the experimental data, which allowed the computation of the kinetic parameters of the pozzolanic reaction (reaction rate constant and free energy of activation) that rigorously characterised the pozzolanic activity of the materials. The results show that SCBCA demonstrated reactivity and good pozzolanic qualities in the range 800–1000°C.

Key concepts: Pozzolanic activity, Pozzolanic reaction, Pozzolan, Calcium hydroxide, Materials science, Bagasse, Activation energy, Chemical engineering

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