2000Chemical CommunicationsRequires access

Host–guest chemistry of calixarene capsules

JULIUS JUN. REBEK

Open publisher page 398 citations

Abstract

Reversible encapsulation is one of the more recent forms of molecular recognition. Small molecule targets are completely surrounded by larger molecular assemblies and steric barriers keep the guest from escaping the host. Calix[4]arenes make useful modules for capsule construction and the review traces their history. Applications in physical organic chemistry, materials science and spectroscopy are described.

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What this paper is about

Reversible encapsulation is one of the more recent forms of molecular recognition. Small molecule targets are completely surrounded by larger molecular assemblies and steric barriers keep the guest from escaping the host. Calix[4]arenes make useful modules for capsule construction and the review traces their history. Applications in physical organic chemistry, materials science and spectroscopy are described.

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OpenAlex reports 398 citations for this work. Citation counts describe recorded attention and do not establish research quality.

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Available abstract

Reversible encapsulation is one of the more recent forms of molecular recognition. Small molecule targets are completely surrounded by larger molecular assemblies and steric barriers keep the guest from escaping the host. Calix[4]arenes make useful modules for capsule construction and the review traces their history. Applications in physical organic chemistry, materials science and spectroscopy are described.

Key concepts: Calixarene, Steric effects, Host–guest chemistry, Chemistry, Molecule, Host (biology), Molecular recognition, Nanotechnology

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