1954Journal of Applied ChemistryRequires access

New ω‐substituted anisoles. VII. Aryloxymethyl thiocyanates

H. J. Barber, H. J. Cottrell, M. B. Green

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Abstract

Abstract Phenoxymethyl and phenylthiomethyl chlorides are readily converted into the corresponding thiocyanates by interaction with potassium thiocyanate in acetone or alcohol. The compounds thus obtained possess the thiocyanate and not the isothiocyanate structure. 2: 4‐Dichlorophen‐oxymethyl thiocyanate undergoes isomerization to the isothiocyanate on distillation under reduced pressure.

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Abstract Phenoxymethyl and phenylthiomethyl chlorides are readily converted into the corresponding thiocyanates by interaction with potassium thiocyanate in acetone or alcohol. The compounds thus obtained possess the thiocyanate and not the isothiocyanate structure. 2: 4‐Dichlorophen‐oxymethyl thiocyanate undergoes isomerization to the isothiocyanate on distillation under reduced pressure.

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Available abstract

Abstract Phenoxymethyl and phenylthiomethyl chlorides are readily converted into the corresponding thiocyanates by interaction with potassium thiocyanate in acetone or alcohol. The compounds thus obtained possess the thiocyanate and not the isothiocyanate structure. 2: 4‐Dichlorophen‐oxymethyl thiocyanate undergoes isomerization to the isothiocyanate on distillation under reduced pressure.

Key concepts: Thiocyanate, Potassium thiocyanate, Acetone, Chemistry, Isomerization, Alcohol, Inorganic chemistry, Organic chemistry

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