New ω‐substituted anisoles. VII. Aryloxymethyl thiocyanates
H. J. Barber, H. J. Cottrell, M. B. Green
Abstract
H. J. Barber, H. J. Cottrell, M. B. Green
Abstract
Abstract Phenoxymethyl and phenylthiomethyl chlorides are readily converted into the corresponding thiocyanates by interaction with potassium thiocyanate in acetone or alcohol. The compounds thus obtained possess the thiocyanate and not the isothiocyanate structure. 2: 4‐Dichlorophen‐oxymethyl thiocyanate undergoes isomerization to the isothiocyanate on distillation under reduced pressure.
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Abstract Phenoxymethyl and phenylthiomethyl chlorides are readily converted into the corresponding thiocyanates by interaction with potassium thiocyanate in acetone or alcohol. The compounds thus obtained possess the thiocyanate and not the isothiocyanate structure. 2: 4‐Dichlorophen‐oxymethyl thiocyanate undergoes isomerization to the isothiocyanate on distillation under reduced pressure.
Key concepts: Thiocyanate, Potassium thiocyanate, Acetone, Chemistry, Isomerization, Alcohol, Inorganic chemistry, Organic chemistry