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Compressed Liquid Densities, Saturated Liquid Densities, and Vapor Pressures of 1,1-Difluoroethane

Dana R. Defibaugh, Graham Morrison

Open publisher page 21 citations

Abstract

The compressed liquid densities and vapor pressures of 1,1-difluoroethane (HFC-152a) have been measured, correlated, and compared with other data. The liquid densities were measured with a combined standard uncertainty of ±0.05% using a vibrating tube densimeter over a temperature range of 243 K to 371 K and at pressures from near the saturated vapor pressure to 6500 kPa; thus the data extend nearly to the critical point ( T c = 386.41 K and P c = 4514.7 kPa). The vapor pressures were measured with a combined standard uncertainty of ±0.02% using a stainless steel ebulliometer in the temperature range from 280 K to 335 K. Saturated liquid densities were calculated by extrapolating the compressed liquid isotherms to the saturation pressure.

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What this paper is about

The compressed liquid densities and vapor pressures of 1,1-difluoroethane (HFC-152a) have been measured, correlated, and compared with other data. The liquid densities were measured with a combined standard uncertainty of ±0.05% using a vibrating tube densimeter over a temperature range of 243 K to 371 K and at pressures from near the saturated vapor pressure to 6500 kPa; thus the data extend nearly to the critical point ( T c = 386.41 K and P c = 4514.7 kPa). The vapor pressures were measured with a combined standard uncertainty of ±0.02% using a stainless steel ebulliometer in the temperature range from 280 K to 335 K. Saturated liquid densities were calculated by extrapolating the compressed liquid isotherms to the saturation pressure.

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Available abstract

The compressed liquid densities and vapor pressures of 1,1-difluoroethane (HFC-152a) have been measured, correlated, and compared with other data. The liquid densities were measured with a combined standard uncertainty of ±0.05% using a vibrating tube densimeter over a temperature range of 243 K to 371 K and at pressures from near the saturated vapor pressure to 6500 kPa; thus the data extend nearly to the critical point ( T c = 386.41 K and P c = 4514.7 kPa). The vapor pressures were measured with a combined standard uncertainty of ±0.02% using a stainless steel ebulliometer in the temperature range from 280 K to 335 K. Saturated liquid densities were calculated by extrapolating the compressed liquid isotherms to the saturation pressure.

Key concepts: Compressed fluid, Chemistry, Vapor pressure, Vapor–liquid equilibrium, Saturation (graph theory), Thermodynamics, Analytical Chemistry (journal), Boiling point

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