2005•The Journal of Physical Chemistry ARequires access
Noble Gas−Transition Metal Complexes: Coordination of ScO+ by Multiple Ar, Kr, and Xe Atoms in Noble Gas Matrixes
Yanying Zhao, Guanjun Wang, Mohua Chen, Mingfei Zhou
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Abstract
The combination of matrix isolation infrared spectroscopic and density functional calculation results provides strong evidence that the transition metal monoxide cation, ScO+, coordinates five noble gas atoms in forming the [ScO(Ng)5]+ (Ng = Ar, Kr, or Xe) complexes in noble gas matrixes.