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Intermediacy of aryl radicals and arylmetal compounds in reductive dehalogenation of halogenoarenes with lithium aluminium hydride

ATHELSTAN L. J. BECKWITH, Swee Hock Goh

Open publisher page 17 citations

Abstract

Reduction of o-allyloxybromobenzene (1) with lithium aluminium hydride proceeds by two competing pathways; one involving aryl radicals is promoted by oxygen, the other affords initially an arylmetal compound.

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Reduction of o-allyloxybromobenzene (1) with lithium aluminium hydride proceeds by two competing pathways; one involving aryl radicals is promoted by oxygen, the other affords initially an arylmetal compound.

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OpenAlex reports 17 citations for this work. Citation counts describe recorded attention and do not establish research quality.

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Available abstract

Reduction of o-allyloxybromobenzene (1) with lithium aluminium hydride proceeds by two competing pathways; one involving aryl radicals is promoted by oxygen, the other affords initially an arylmetal compound.

Key concepts: ALUMINUM HYDRIDE, Aryl, Lithium aluminium hydride, Halogenation, Chemistry, Lithium (medication), Radical, Hydride

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