Masahiro Murakami, Hiroyuki Minamikawa, Teruaki Mukaiyama
Abstract
Abstract β-Alkoxy ketones are synthesized in good yields by the reaction of alkyl enol ethers with acetals in the presence of a catalytic amount of trityl salts. Of enol ethers, methoxymethyl (MOM) enol ether exhibits an enhanced reactivity as a nucleophile.
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Abstract β-Alkoxy ketones are synthesized in good yields by the reaction of alkyl enol ethers with acetals in the presence of a catalytic amount of trityl salts. Of enol ethers, methoxymethyl (MOM) enol ether exhibits an enhanced reactivity as a nucleophile.
Key concepts: Chemistry, Aldol reaction, Enol, Catalysis, Alkyl, Organic chemistry, Acetal, Enol ether