2012Journal of the Ceramic Society of JapanOpen access

Influence of powder characteristics on the electrical resistivity of SiC ceramics

Kwang-Young Lim, Young‐Wook Kim, Kwang Joo Kim

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Abstract

Four types of commercially available SiC powders were hot-pressed with 1 wt % Dy2O3–AlN additives in a 3:2 molar ratio. Three submicron-sized SiC powders could be densified so as to have a relative density higher than 98%, whereas a micron-sized SiC powder showed limited densification up to 93.5%. SiC ceramics fabricated from β-SiC powders exhibited electrical resistivities (∼10−1 Ω·cm) that were lower than those from α-SiC powders (∼101 Ω·cm). The lower electrical resistivity of the SiC ceramics fabricated from β-SiC powders could be attributed to a higher carrier density and enhanced charge mobility when compared to the SiC ceramics from α-SiC powders.

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Four types of commercially available SiC powders were hot-pressed with 1 wt % Dy2O3–AlN additives in a 3:2 molar ratio. Three submicron-sized SiC powders could be densified so as to have a relative density higher than 98%, whereas a micron-sized SiC powder showed limited densification up to 93.5%. SiC ceramics fabricated from β-SiC powders exhibited electrical resistivities (∼10−1 Ω·cm) that were lower than those from α-SiC powders (∼101 Ω·cm). The lower electrical resistivity of the SiC ceramics fabricated from β-SiC powders could be attributed to a higher carrier density and enhanced charge mobility when compared to the SiC ceramics from α-SiC powders.

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Available abstract

Four types of commercially available SiC powders were hot-pressed with 1 wt % Dy2O3–AlN additives in a 3:2 molar ratio. Three submicron-sized SiC powders could be densified so as to have a relative density higher than 98%, whereas a micron-sized SiC powder showed limited densification up to 93.5%. SiC ceramics fabricated from β-SiC powders exhibited electrical resistivities (∼10−1 Ω·cm) that were lower than those from α-SiC powders (∼101 Ω·cm). The lower electrical resistivity of the SiC ceramics fabricated from β-SiC powders could be attributed to a higher carrier density and enhanced charge mobility when compared to the SiC ceramics from α-SiC powders.

Key concepts: Materials science, Electrical resistivity and conductivity, Ceramic, Composite material, Relative density, Silicon carbide, Microstructure, Electrical engineering

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