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1994•Acta Crystallographica Section C Crystal Structure CommunicationsRequires access

A 3-phenylsulfinyl-1-phenylsulfonylindole

Roy L. Beddoes, Jason G. Kettle, J. A. Joule

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Abstract

The title compound 2-(3,4-dihydro-2H-pyrrol-5-yl)-1-phenylsulfonylindol-3-yl phenyl sulfoxide, C 24 H 20 N 2 O 3 S 2 , was isolated, together with 3-chloro-2-(3,4-dihydro-2H-pyrrol-5-yl)-1-phenylsulfonylindole, from the treatment of 2-(3,4-dihydro-2H-pyrrol-5-yl)indole with sodium hydride and phenylsulfonylchloride, showing that the latter can act as an electrophilic chlorinating agent and as a source of an electrophilic phenylsulfinylating species

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What this paper is about

The title compound 2-(3,4-dihydro-2H-pyrrol-5-yl)-1-phenylsulfonylindol-3-yl phenyl sulfoxide, C 24 H 20 N 2 O 3 S 2 , was isolated, together with 3-chloro-2-(3,4-dihydro-2H-pyrrol-5-yl)-1-phenylsulfonylindole, from the treatment of 2-(3,4-dihydro-2H-pyrrol-5-yl)indole with sodium hydride and phenylsulfonylchloride, showing that the latter can act as an electrophilic chlorinating agent and as a source of an electrophilic phenylsulfinylating species

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Available abstract

The title compound 2-(3,4-dihydro-2H-pyrrol-5-yl)-1-phenylsulfonylindol-3-yl phenyl sulfoxide, C 24 H 20 N 2 O 3 S 2 , was isolated, together with 3-chloro-2-(3,4-dihydro-2H-pyrrol-5-yl)-1-phenylsulfonylindole, from the treatment of 2-(3,4-dihydro-2H-pyrrol-5-yl)indole with sodium hydride and phenylsulfonylchloride, showing that the latter can act as an electrophilic chlorinating agent and as a source of an electrophilic phenylsulfinylating species

Key concepts: Electrophile, Sodium hydride, Indole test, Sulfoxide, Chemistry, Hydride, Medicinal chemistry, Combinatorial chemistry

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