Nucleophilicity of halide ions in molten quaternary ammonium salts
John Edward Gordon, Pothen Varughese
Abstract
John Edward Gordon, Pothen Varughese
Abstract
The relative rates of nucleophilic displacement by halide ions from tetra-n-pentylammonium cations in the molten tetrapentylammonium salts at 180°(Cl–:Br–:I–= 620:7·7:1) reflect the enhanced nucleophilicity expected for unsolvated, unassociated halide ions.
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The relative rates of nucleophilic displacement by halide ions from tetra-n-pentylammonium cations in the molten tetrapentylammonium salts at 180°(Cl–:Br–:I–= 620:7·7:1) reflect the enhanced nucleophilicity expected for unsolvated, unassociated halide ions.
Key concepts: Halide, Nucleophile, Chemistry, Ammonium, Ion, Inorganic chemistry, Medicinal chemistry, Organic chemistry