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On the Connection Between the Resolvent Methods and Partitioning Technique, Rational Approximations, and Perturbation Theory

Per‐Olov Löwdin

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Abstract

In the resolvent methods for solving the Schrödinger equation, the eigenvalues are represented by simple poles of the so-called Weinstein function, whereas the eigenfunctions are represented by expressions of the form ∞/∞. It is shown that there exists a simple identity which permits the evaluation of the eigenfunction, and which shows the connection between the resolvent methods and partitioning technique, rational approximations, and perturbation theory. It is also shown that this identity may be extended to the solution of the Liouville equation.

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What this paper is about

In the resolvent methods for solving the Schrödinger equation, the eigenvalues are represented by simple poles of the so-called Weinstein function, whereas the eigenfunctions are represented by expressions of the form ∞/∞. It is shown that there exists a simple identity which permits the evaluation of the eigenfunction, and which shows the connection between the resolvent methods and partitioning technique, rational approximations, and perturbation theory. It is also shown that this identity may be extended to the solution of the Liouville equation.

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Available abstract

In the resolvent methods for solving the Schrödinger equation, the eigenvalues are represented by simple poles of the so-called Weinstein function, whereas the eigenfunctions are represented by expressions of the form ∞/∞. It is shown that there exists a simple identity which permits the evaluation of the eigenfunction, and which shows the connection between the resolvent methods and partitioning technique, rational approximations, and perturbation theory. It is also shown that this identity may be extended to the solution of the Liouville equation.

Key concepts: Resolvent, Eigenfunction, Eigenvalues and eigenvectors, Connection (principal bundle), Resolvent formalism, Simple (philosophy), Mathematics, Perturbation (astronomy)

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