1975The Journal of Chemical PhysicsRequires access

Spectroscopic studies on napththalene in the vapor phase. III. Phosphorescence and intersystem crossing yields of single vibronic levels

H. Gattermann, Manfred Stockburger

Open publisher page 48 citations

Abstract

Gas-phase phosphorescence spectra of naphthalene-h8 and -d8 are reported. A triplet lifetime of 4.2 msec was derived from the 000 band of the n-h8 phosphorescence. Intersystem crossing yields of single vibronic levels in S1 were determined from excitation spectra of biacetyl phosphorescence.

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Gas-phase phosphorescence spectra of naphthalene-h8 and -d8 are reported. A triplet lifetime of 4.2 msec was derived from the 000 band of the n-h8 phosphorescence. Intersystem crossing yields of single vibronic levels in S1 were determined from excitation spectra of biacetyl phosphorescence.

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Available abstract

Gas-phase phosphorescence spectra of naphthalene-h8 and -d8 are reported. A triplet lifetime of 4.2 msec was derived from the 000 band of the n-h8 phosphorescence. Intersystem crossing yields of single vibronic levels in S1 were determined from excitation spectra of biacetyl phosphorescence.

Key concepts: Intersystem crossing, Phosphorescence, Photochemistry, Chemistry, Spectral line, Naphthalene, Gas phase, Excitation

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