Spectroscopic studies on napththalene in the vapor phase. III. Phosphorescence and intersystem crossing yields of single vibronic levels
H. Gattermann, Manfred Stockburger
Abstract
H. Gattermann, Manfred Stockburger
Abstract
Gas-phase phosphorescence spectra of naphthalene-h8 and -d8 are reported. A triplet lifetime of 4.2 msec was derived from the 000 band of the n-h8 phosphorescence. Intersystem crossing yields of single vibronic levels in S1 were determined from excitation spectra of biacetyl phosphorescence.
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Gas-phase phosphorescence spectra of naphthalene-h8 and -d8 are reported. A triplet lifetime of 4.2 msec was derived from the 000 band of the n-h8 phosphorescence. Intersystem crossing yields of single vibronic levels in S1 were determined from excitation spectra of biacetyl phosphorescence.
Key concepts: Intersystem crossing, Phosphorescence, Photochemistry, Chemistry, Spectral line, Naphthalene, Gas phase, Excitation