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Variational calculations on the helium isoelectronic sequence

David Freund, Barton D. Huxtable, John D. Morgan

Open publisher page 273 citations

Abstract

We have performed variational calculations on the helium isoelectronic sequence for values of the nuclear charge $Z$ ranging from 1 to 10. The basis used is a modification of that employed by Frankowski and Pekeris in 1966, whose calculation has not been superseded before now. Using 230-term wave functions, we obtain for $Z=2$ through 10 variational energies accurate to better than a few parts in ${10}^{13}$. Our results illustrate the importance of using basis functions which have the same analytic structure as the exact wave function being approximated.

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We have performed variational calculations on the helium isoelectronic sequence for values of the nuclear charge $Z$ ranging from 1 to 10. The basis used is a modification of that employed by Frankowski and Pekeris in 1966, whose calculation has not been superseded before now. Using 230-term wave functions, we obtain for $Z=2$ through 10 variational energies accurate to better than a few parts in ${10}^{13}$. Our results illustrate the importance of using basis functions which have the same analytic structure as the exact wave function being approximated.

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Available abstract

We have performed variational calculations on the helium isoelectronic sequence for values of the nuclear charge $Z$ ranging from 1 to 10. The basis used is a modification of that employed by Frankowski and Pekeris in 1966, whose calculation has not been superseded before now. Using 230-term wave functions, we obtain for $Z=2$ through 10 variational energies accurate to better than a few parts in ${10}^{13}$. Our results illustrate the importance of using basis functions which have the same analytic structure as the exact wave function being approximated.

Key concepts: Helium, Wave function, Sequence (biology), Physics, Basis (linear algebra), Variational method, Atomic physics, Effective nuclear charge

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