The interaction of chloranil with aliphatic amines
R. Foster
Abstract
R. Foster
Abstract
Abstract Although substitution of chlorine usually occurs in the interaction of chloranil with aliphatic amines, solutions of chloranil in pure triethylamine yield a product which appears to be a salt, the anion of which is the free radical semiquinone ion derived from chloranil. In acetone solution this salt decomposes to yield 2,3,5‐trichloro‐6‐(2′‐diethylaminovinyl)‐p‐benzoquinone.
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Abstract Although substitution of chlorine usually occurs in the interaction of chloranil with aliphatic amines, solutions of chloranil in pure triethylamine yield a product which appears to be a salt, the anion of which is the free radical semiquinone ion derived from chloranil. In acetone solution this salt decomposes to yield 2,3,5‐trichloro‐6‐(2′‐diethylaminovinyl)‐p‐benzoquinone.
Key concepts: Chloranil, Triethylamine, Semiquinone, Chemistry, Yield (engineering), Salt (chemistry), Triphenylamine, Chlorine