Blend polyolefin elastomers based on a stereoblock elastomeric PP
Eduard V Prut, Polina M. Nedorezova, ALLA N. KLYAMKINA, T. I. Medintseva, Lubov A. Zhorina, Olga Kuznetsova, A. V. Chapurina, Alexander M. Aladyshev
Abstract
Eduard V Prut, Polina M. Nedorezova, ALLA N. KLYAMKINA, T. I. Medintseva, Lubov A. Zhorina, Olga Kuznetsova, A. V. Chapurina, Alexander M. Aladyshev
Abstract
The principles of the creation of new blend polyolefin elastomers with a controlled complex of properties based on a stereoblock elastomeric PP synthesized in the presence of asymmetric ansa-metallocenes are proposed. Original blend polymer materials with reduced hardness that are based on elastomeric PPs with different characteristics and a 50–70 wt % oil-extended ternary ethylene-propylene-diene elastomer were prepared through the method of dynamic vulcanization. The molecular-mass characteristics of PP have a considerable effect on the rheological properties of polyolefin elastomers. For successful processing of the resulting blends, the pristine component, the elastomeric PP, must have a weight-average molecular mass of M w = (8−14) × 104 and a low crystallinity.
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The principles of the creation of new blend polyolefin elastomers with a controlled complex of properties based on a stereoblock elastomeric PP synthesized in the presence of asymmetric ansa-metallocenes are proposed. Original blend polymer materials with reduced hardness that are based on elastomeric PPs with different characteristics and a 50–70 wt % oil-extended ternary ethylene-propylene-diene elastomer were prepared through the method of dynamic vulcanization. The molecular-mass characteristics of PP have a considerable effect on the rheological properties of polyolefin elastomers. For successful processing of the resulting blends, the pristine component, the elastomeric PP, must have a weight-average molecular mass of M w = (8−14) × 104 and a low crystallinity.
Key concepts: Polyolefin, Elastomer, Vulcanization, Materials science, Polymer science, Crystallinity, Thermoplastic elastomer, Composite material