Morgan Morris, Anthony John Waring
Abstract
The photochemically-induced rearrangement of some cyclohexa-2,4-dienones to bicyclo[3,1,0]hex-3-en-2-ones occurs by a general stereospecific ring opening to a keten, which is followed by a stereospecific thermal cyclisation.
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The photochemically-induced rearrangement of some cyclohexa-2,4-dienones to bicyclo[3,1,0]hex-3-en-2-ones occurs by a general stereospecific ring opening to a keten, which is followed by a stereospecific thermal cyclisation.
Key concepts: Stereospecificity, Chemistry, Ring (chemistry), Stereochemistry, Photochemistry, Medicinal chemistry, Organic chemistry, Catalysis