1978•Journal of the Chemical Society Chemical CommunicationsRequires access

Long-range deuterium-induced 13C nuclear magnetic resonance isotope shifts for single assignment and determination of deuteriation site in cyclodecanone isotopomers

Félix W. Wehrli, Dragoslav Jeremi, Mihailo Lj. Mihailovíć, Slobodan Milosavljevi

Abstract

The incremental 13C chemical shifts observed upon replacement of protons by deuterons in cyclo-decanones give line assignments which are not otherwise obtainable; apart from directly bonded carbon, isotope shifts were detected across 2, 3, 4, 5, and 6 bonds.

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Key concepts: Isotopomers, Deuterium, Isotope, Chemistry, Kinetic isotope effect, Range (aeronautics), Carbon-13, Isotopes of carbon