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2010•The Journal of Organic ChemistryRequires access

Photoactivated Racemization Catalyst for Dynamic Kinetic Resolution of Secondary Alcohols

Youngshil Do, In-Chul Hwang, Mahn‐Joo Kim, Jaiwook Park

Open publisher page 35 citations

Abstract

Household fluorescent light activates a diruthenium complex to generate catalytic species highly active for the racemization of secondary alcohols under ambient conditions. This catalyst system is applicable for the chemoenzymatic dynamic kinetic resolution of racemic alcohols to give optically pure acetates under mild conditions.

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What this paper is about

Household fluorescent light activates a diruthenium complex to generate catalytic species highly active for the racemization of secondary alcohols under ambient conditions. This catalyst system is applicable for the chemoenzymatic dynamic kinetic resolution of racemic alcohols to give optically pure acetates under mild conditions.

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OpenAlex reports 35 citations for this work. Citation counts describe recorded attention and do not establish research quality.

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Available abstract

Household fluorescent light activates a diruthenium complex to generate catalytic species highly active for the racemization of secondary alcohols under ambient conditions. This catalyst system is applicable for the chemoenzymatic dynamic kinetic resolution of racemic alcohols to give optically pure acetates under mild conditions.

Key concepts: Racemization, Kinetic resolution, Chemistry, Catalysis, Kinetic energy, Fluorescence, Optically active, Organic chemistry

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