1972Journal of the Chemical Society Chemical CommunicationsRequires access

Carbanionic character of decafluorobenzhydryl bromide. Behaviour towards nucleophiles

Robert Filler, Frank P. Avonda

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Abstract

Decafluorobenzhydryl bromide (1) reacts with nucleophiles to give 1,1,2,2-tetrakis(pentafluorophenyl)-ethane (2) as the predominant product; there is no evidence of products derived from initial nucleophilic displacement on the carbon of (1).

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What this paper is about

Decafluorobenzhydryl bromide (1) reacts with nucleophiles to give 1,1,2,2-tetrakis(pentafluorophenyl)-ethane (2) as the predominant product; there is no evidence of products derived from initial nucleophilic displacement on the carbon of (1).

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Available abstract

Decafluorobenzhydryl bromide (1) reacts with nucleophiles to give 1,1,2,2-tetrakis(pentafluorophenyl)-ethane (2) as the predominant product; there is no evidence of products derived from initial nucleophilic displacement on the carbon of (1).

Key concepts: Nucleophile, Bromide, Chemistry, Character (mathematics), Displacement (psychology), Medicinal chemistry, Carbon fibers, Product (mathematics)

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