Clathrate Hydrates in the Water–Tetrahydropyran System at High Pressure
Yuri A. Dyadin, Tamara V. Mikina, Fridrikh V. Zhurko, Yurii I. Mironov, A. V. Manuilov, Grigorii Skripko
Abstract
Yuri A. Dyadin, Tamara V. Mikina, Fridrikh V. Zhurko, Yurii I. Mironov, A. V. Manuilov, Grigorii Skripko
Abstract
Tetrahydropyran (THP) forms a clathrate hydrate THP·17H2O of cubic structure II which melts at P = 1 atm, T= – 0.8°C decomposing into two liquids with an upper consolute temperature of dissolution of 226 °C. It is destabilized by pressure and at P > 1.15 kbar, T= – 4.3°C cubic structure I hydrate appears to become stable.
OpenAlex reports 5 citations for this work. Citation counts describe recorded attention and do not establish research quality.
A contribution statement is not available in the OpenAlex record.
Method details are not available in the OpenAlex metadata.
Findings are not separately available in the OpenAlex metadata.
Limitations are not available in the OpenAlex metadata.
Application details are not available in the OpenAlex metadata.
Tetrahydropyran (THP) forms a clathrate hydrate THP·17H2O of cubic structure II which melts at P = 1 atm, T= – 0.8°C decomposing into two liquids with an upper consolute temperature of dissolution of 226 °C. It is destabilized by pressure and at P > 1.15 kbar, T= – 4.3°C cubic structure I hydrate appears to become stable.
Key concepts: Tetrahydropyran, Clathrate hydrate, Chemistry, Dissolution, Hydrate, Thermodynamics, Crystallography, Physical chemistry