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Clathrate Hydrates in the Water–Tetrahydropyran System at High Pressure

Yuri A. Dyadin, Tamara V. Mikina, Fridrikh V. Zhurko, Yurii I. Mironov, A. V. Manuilov, Grigorii Skripko

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Abstract

Tetrahydropyran (THP) forms a clathrate hydrate THP·17H2O of cubic structure II which melts at P = 1 atm, T= – 0.8°C decomposing into two liquids with an upper consolute temperature of dissolution of 226 °C. It is destabilized by pressure and at P > 1.15 kbar, T= – 4.3°C cubic structure I hydrate appears to become stable.

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What this paper is about

Tetrahydropyran (THP) forms a clathrate hydrate THP·17H2O of cubic structure II which melts at P = 1 atm, T= – 0.8°C decomposing into two liquids with an upper consolute temperature of dissolution of 226 °C. It is destabilized by pressure and at P > 1.15 kbar, T= – 4.3°C cubic structure I hydrate appears to become stable.

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Available abstract

Tetrahydropyran (THP) forms a clathrate hydrate THP·17H2O of cubic structure II which melts at P = 1 atm, T= – 0.8°C decomposing into two liquids with an upper consolute temperature of dissolution of 226 °C. It is destabilized by pressure and at P > 1.15 kbar, T= – 4.3°C cubic structure I hydrate appears to become stable.

Key concepts: Tetrahydropyran, Clathrate hydrate, Chemistry, Dissolution, Hydrate, Thermodynamics, Crystallography, Physical chemistry

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