1980•Journal de physiqueOpen access

Excitation of 2 1S, 2 1P and 3 1P, 3 3P levels of helium in He+ on He collisions at a few hundreds eV

G. Rahmat, Gergo Vassilev, J. Baudon

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Abstract

The excitations of Helium on 2 1S, 2 1P and 3 1P, 3 3P levels in He+ on He collisions at low energy are investigated experimentally. The data are interpreted in the frame of a semi-diabatic description of He+2 , using a semi-classical treatment of the collision. 2 1P differential cross sections at 100 and 150 eV (Lab) and angular ion-photon correlation functions at 100 eV (Lab) and laboratory scattering angles of 10.25 and 12.5 deg. have been measured using an ion-photon coincidence technique. These data, together with previous measurements on 2 1S excitation, show that channels 2 1P and 2 1S are coupled by a secondary rotational mechanism. The effects of such mechanisms on the differential and total cross sections of both excited channels are examined in the général case using a 3 state model including two Σg states and one Πg state. 3 3P differential cross sections have been measured at 120 and 150 eV (Lab) by detecting in coincidence the scattered ion and the 3 3P-2 3S photon (λ = 3 889 Å). Coincidence polarization measurements at 150 eV, 13.5 deg. (Lab) show that the symmetry of the final molecular state leading to 3 3P is Σ. In spite of the large number of secondary mechanisms involved in the 3 3P excitation (which produce Rosenthal effects in the total cross section), it is shown that an extremely simplified two state calculation is able to give the général features of 3 3P differential cross section, which are mainly determined by the primary mechanism. A similar coincidence technique operating on the 3 1P-2 1S line (λ = 5 016 Å) has been used to measure the 3 1P differential cross section at 150 eV (Lab). A calculation of the 3 1P excitation using a 3 state model is consistent with the polarization measurements at 150 eV, 12, 13.5 and 15.5 deg. (Lab) which show that the symmetry of the final molecular state is Π.

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What this paper is about

The excitations of Helium on 2 1S, 2 1P and 3 1P, 3 3P levels in He+ on He collisions at low energy are investigated experimentally. The data are interpreted in the frame of a semi-diabatic description of He+2 , using a semi-classical treatment of the collision. 2 1P differential cross sections at 100 and 150 eV (Lab) and angular ion-photon correlation functions at 100 eV (Lab) and laboratory scattering angles of 10.25 and 12.5 deg. have been measured using an ion-photon coincidence technique. These data, together with previous measurements on 2 1S excitation, show that channels 2 1P and 2 1S are coupled by a secondary rotational mechanism. The effects of such mechanisms on the differential and total cross sections of both excited channels are examined in the général case using a 3 state model including two Σg states and one Πg state. 3 3P differential cross sections have been measured at 120 and 150 eV (Lab) by detecting in coincidence the scattered ion and the 3 3P-2 3S photon (λ = 3 889 Å). Coincidence polarization measurements at 150 eV, 13.5 deg. (Lab) show that the symmetry of the final molecular state leading to 3 3P is Σ. In spite of the large number of secondary mechanisms involved in the 3 3P excitation (which produce Rosenthal effects in the total cross section), it is shown that an extremely simplified two state calculation is able to give the général features of 3 3P differential cross section, which are mainly determined by the primary mechanism. A similar coincidence technique operating on the 3 1P-2 1S line (λ = 5 016 Å) has been used to measure the 3 1P differential cross section at 150 eV (Lab). A calculation of the 3 1P excitation using a 3 state model is consistent with the polarization measurements at 150 eV, 12, 13.5 and 15.5 deg. (Lab) which show that the symmetry of the final molecular state is Π.

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Available abstract

The excitations of Helium on 2 1S, 2 1P and 3 1P, 3 3P levels in He+ on He collisions at low energy are investigated experimentally. The data are interpreted in the frame of a semi-diabatic description of He+2 , using a semi-classical treatment of the collision. 2 1P differential cross sections at 100 and 150 eV (Lab) and angular ion-photon correlation functions at 100 eV (Lab) and laboratory scattering angles of 10.25 and 12.5 deg. have been measured using an ion-photon coincidence technique. These data, together with previous measurements on 2 1S excitation, show that channels 2 1P and 2 1S are coupled by a secondary rotational mechanism. The effects of such mechanisms on the differential and total cross sections of both excited channels are examined in the général case using a 3 state model including two Σg states and one Πg state. 3 3P differential cross sections have been measured at 120 and 150 eV (Lab) by detecting in coincidence the scattered ion and the 3 3P-2 3S photon (λ = 3 889 Å). Coincidence polarization measurements at 150 eV, 13.5 deg. (Lab) show that the symmetry of the final molecular state leading to 3 3P is Σ. In spite of the large number of secondary mechanisms involved in the 3 3P excitation (which produce Rosenthal effects in the total cross section), it is shown that an extremely simplified two state calculation is able to give the général features of 3 3P differential cross section, which are mainly determined by the primary mechanism. A similar coincidence technique operating on the 3 1P-2 1S line (λ = 5 016 Å) has been used to measure the 3 1P differential cross section at 150 eV (Lab). A calculation of the 3 1P excitation using a 3 state model is consistent with the polarization measurements at 150 eV, 12, 13.5 and 15.5 deg. (Lab) which show that the symmetry of the final molecular state is Π.

Key concepts: Helium, Excitation, Atomic physics, Physics, Materials science, Chemistry, Quantum mechanics

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Excitation of 2 1S, 2 1P and 3 1P, 3 3P levels of helium in He+ on He collisions at a few hundreds eV — Research Paper | ScholarLens