The Stereochemistry of the Cleavage of Steroidal Epoxides by Ceric Ammonium Nitrate
James R. Hanson, Mickael Troussier, Cavit Uyanık, Florence Viel
Abstract
James R. Hanson, Mickael Troussier, Cavit Uyanık, Florence Viel
Abstract
The cleavage of unhindered steroidal epoxides by ceric ammonium nitrate affords the trans diaxial β-nitrato alcohols but other products are obtained from more hindered epoxides.
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The cleavage of unhindered steroidal epoxides by ceric ammonium nitrate affords the trans diaxial β-nitrato alcohols but other products are obtained from more hindered epoxides.
Key concepts: Ceric ammonium nitrate, Chemistry, Cleavage (geology), Ammonium, Nitrate, Epoxide, Ammonium nitrate, Organic chemistry