1998Journal of Chemical Research SynopsesRequires access

The Stereochemistry of the Cleavage of Steroidal Epoxides by Ceric Ammonium Nitrate

James R. Hanson, Mickael Troussier, Cavit Uyanık, Florence Viel

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Abstract

The cleavage of unhindered steroidal epoxides by ceric ammonium nitrate affords the trans diaxial β-nitrato alcohols but other products are obtained from more hindered epoxides.

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What this paper is about

The cleavage of unhindered steroidal epoxides by ceric ammonium nitrate affords the trans diaxial β-nitrato alcohols but other products are obtained from more hindered epoxides.

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Available abstract

The cleavage of unhindered steroidal epoxides by ceric ammonium nitrate affords the trans diaxial β-nitrato alcohols but other products are obtained from more hindered epoxides.

Key concepts: Ceric ammonium nitrate, Chemistry, Cleavage (geology), Ammonium, Nitrate, Epoxide, Ammonium nitrate, Organic chemistry

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