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1995•Acta Crystallographica Section C Crystal Structure CommunicationsRequires access

μ-(1,2,5,6-η:3,4,7,8-η)-1,3,5,7-Cyclooctatetraene-bis[dimethylplatinum(II)]

J. R. Doyle, N. C. Baenziger

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Abstract

μ-(1,2,5,6-η:3,4,7,8-η)-1,3,5,7-Cyclooctatetraene-bis[dimethylplatinum(II)], [Pt 2 (C 8 H 8 )(CH 3 ) 4 ], consists of two Pt(CH 3 ) 2 groups bridged by a single cyclooctatetraene molecule. The coordination about each Pt atom is approximately square planar, if each olefinic group is considered as a single ligand. The molecule contains a twofold axis passing through the Pt atoms and the center of the cyclooctatetraene molecule.

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μ-(1,2,5,6-η:3,4,7,8-η)-1,3,5,7-Cyclooctatetraene-bis[dimethylplatinum(II)], [Pt 2 (C 8 H 8 )(CH 3 ) 4 ], consists of two Pt(CH 3 ) 2 groups bridged by a single cyclooctatetraene molecule. The coordination about each Pt atom is approximately square planar, if each olefinic group is considered as a single ligand. The molecule contains a twofold axis passing through the Pt atoms and the center of the cyclooctatetraene molecule.

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Available abstract

μ-(1,2,5,6-η:3,4,7,8-η)-1,3,5,7-Cyclooctatetraene-bis[dimethylplatinum(II)], [Pt 2 (C 8 H 8 )(CH 3 ) 4 ], consists of two Pt(CH 3 ) 2 groups bridged by a single cyclooctatetraene molecule. The coordination about each Pt atom is approximately square planar, if each olefinic group is considered as a single ligand. The molecule contains a twofold axis passing through the Pt atoms and the center of the cyclooctatetraene molecule.

Key concepts: Cyclooctatetraene, Chemistry, Molecule, Crystallography, Atom (system on chip), Stereochemistry, Ligand (biochemistry), Center (category theory)

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