1978Zeitschrift für anorganische und allgemeine ChemieRequires access

Interaction of MnO3F with HF and HCl: Matrix‐isolation infrared spectral studies. The vibrational spectrum of MnO3Cl

E. L. Varetti, Achim Müller

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Abstract

Abstract The interaction MnO3F with HF and HCI was studied by means of matrix‐isolation infrared spectroscopy. Gaseous MnO3F reacts with HCl forming MnO3Cl; some evidence for the probable existence of MnO3FHF complexes is also presented. Isotopic data (35/37Cl) obtained from matrix‐isolation spectra unknown fundamentals (from the spectrum of the solid substance) as well as a vibrational analysis are reported for MnO3Cl.

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Abstract The interaction MnO3F with HF and HCI was studied by means of matrix‐isolation infrared spectroscopy. Gaseous MnO3F reacts with HCl forming MnO3Cl; some evidence for the probable existence of MnO3FHF complexes is also presented. Isotopic data (35/37Cl) obtained from matrix‐isolation spectra unknown fundamentals (from the spectrum of the solid substance) as well as a vibrational analysis are reported for MnO3Cl.

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Available abstract

Abstract The interaction MnO3F with HF and HCI was studied by means of matrix‐isolation infrared spectroscopy. Gaseous MnO3F reacts with HCl forming MnO3Cl; some evidence for the probable existence of MnO3FHF complexes is also presented. Isotopic data (35/37Cl) obtained from matrix‐isolation spectra unknown fundamentals (from the spectrum of the solid substance) as well as a vibrational analysis are reported for MnO3Cl.

Key concepts: Matrix isolation, Infrared spectroscopy, Infrared, Matrix (chemical analysis), Chemistry, Spectral line, Spectroscopy, Physical chemistry

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