1980Journal of the Chemical Society Chemical CommunicationsRequires access

Brominative cyclisation of nerolidol and geranyl-linalool

Tadahiro Kato, Koichi Ishii, Isao Ichinose, Y. Nakai, Takashi Kumagai

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Abstract

(+)-Nerolidol was treated with 2,4,4,6-tetrabromocyclohexa-2,5-dienone to afford the brominative cyclisation products α- and β-snyderols and 3-bromocaparrapi oxide and its 8-epimer; (±)-geranyl-linalool gave the analogous tricyclic ethers.

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What this paper is about

(+)-Nerolidol was treated with 2,4,4,6-tetrabromocyclohexa-2,5-dienone to afford the brominative cyclisation products α- and β-snyderols and 3-bromocaparrapi oxide and its 8-epimer; (±)-geranyl-linalool gave the analogous tricyclic ethers.

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Available abstract

(+)-Nerolidol was treated with 2,4,4,6-tetrabromocyclohexa-2,5-dienone to afford the brominative cyclisation products α- and β-snyderols and 3-bromocaparrapi oxide and its 8-epimer; (±)-geranyl-linalool gave the analogous tricyclic ethers.

Key concepts: Nerolidol, Linalool, Chemistry, Epimer, Organic chemistry, Stereochemistry, Chromatography, Essential oil

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