Remarkable Support Effects of Gallium Compounds on the Activity and Selectivity of Ru Metal Catalyst for Liquid-phase Citral Hydrogenation
Hiroshi Nishiyama, J. Takeuchi, Hiroshi Hayase, Nobuo Saito, Yasunobu Inoue
Abstract
Hiroshi Nishiyama, J. Takeuchi, Hiroshi Hayase, Nobuo Saito, Yasunobu Inoue
Abstract
Abstract Various types of p-block metal oxides and nitrides were employed as catalyst supports for Ru metal in liquid-phase citral hydrogenation. Compounds containing Ga3+ ions, in particular GaOOH, were found to exhibit remarkable support effects on the enhancement of catalytic activity and reaction selectivity for the production of α,β-unsaturated alcohols (nerol and geraniol).
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Abstract Various types of p-block metal oxides and nitrides were employed as catalyst supports for Ru metal in liquid-phase citral hydrogenation. Compounds containing Ga3+ ions, in particular GaOOH, were found to exhibit remarkable support effects on the enhancement of catalytic activity and reaction selectivity for the production of α,β-unsaturated alcohols (nerol and geraniol).
Key concepts: Citral, Nerol, Chemistry, Geraniol, Selectivity, Catalysis, Metal, Organic chemistry