Two Novel Lanostane-Type Triterpenes from the Stem Bark of Abies mariesii
Reiko Tanaka, Hitoshi Aoki, Shun-ich Wada, S. Matsunaga
Abstract
Reiko Tanaka, Hitoshi Aoki, Shun-ich Wada, S. Matsunaga
Abstract
Two novel lanostane-type triterpene lactones, 3alpha, 11alpha-dihydroxy-7-oxolanosta-8,24-dien-26,23(R)-olide (1) and 1alpha,3alpha,11alpha-trihydroxy-7-oxolanosta-8,24-dien-26, 23(R)-olide (2), were isolated from the stem bark of Abies mariesii, together with a known triterpene, 3-oxo-9betaH-lanosta-7,24-dien-26, 23(R)-olide. The structures of 1 and 2 were determined on the basis of 2D NMR techniques.
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Two novel lanostane-type triterpene lactones, 3alpha, 11alpha-dihydroxy-7-oxolanosta-8,24-dien-26,23(R)-olide (1) and 1alpha,3alpha,11alpha-trihydroxy-7-oxolanosta-8,24-dien-26, 23(R)-olide (2), were isolated from the stem bark of Abies mariesii, together with a known triterpene, 3-oxo-9betaH-lanosta-7,24-dien-26, 23(R)-olide. The structures of 1 and 2 were determined on the basis of 2D NMR techniques.
Key concepts: Triterpene, Lanostane, Terpene, Pinaceae, Bark (sound), Stereochemistry, Pharmacognosy, Chemistry